C. E. White said:
ISSUE:
Rough idle, hesitation, poor throttle response, induction backfire and
stalls during cold start/warm up may be caused by the poor volatility of
some high octane premium grade unleaded fuels (91 octane or higher
(R+M)/2). When compared to regular grade unleaded fuel (87 octane
(R+M)/2), high octane premium grade unleaded fuel may cause long crank
time.
That WAS a problem at one time, when alternatives to lead were first
being experimented with to obtain higher octane ratings than 85-87
(R+M)/2. I would date this to probably the mid to late 1980s, just guessing.
The fact that early "high octane" (what a joke!) unleaded fuels had this
problem has in fact lead to a wide-spread misconception that "octane"
and "volatility" are related, and that "high octane" fuel is "less
volatile" than low octane fuel. In general, that is NOT true at all.
Octane rating is a measure of resistance to self-ignition, that is all.
Volatility has no fundamental bearing on the matter. If you were to take
two gasoline base stocks and raise the octane of one sample by using,
say, tetraethyl lead or MMT and leave a second sample alone, the two
samples would have the same volatility (propensity to vaporize at a
given temperature and pressure). However, if gasoline makers use
aromatic hydrocarbons (or non-hydrocarbons for that matter) to increase
the octane rating instead of lead or manganese, then the volatility may
be adversely affected, as it was in 80s era fuels. Today, most gasolines
except the EPA-mandated special brews seem to be very well compensated
for volatility and octane. Using a higher octane rating might be a waste
of money, but with modern fuels it is harmless. And in fact *some*
makers put other goodies like detergent and lubricant additives in their
higher octane fuels, so there may be some advantage to the fuel system
even if the octane rating is of no benefit.